By Jaroslav Sebestik, Milan Reinis, Jan Jezek
Reaping rewards researchers in biochemistry and pharmacology, this booklet describes assorted different types of dendrimers, their biomedical and physico-chemical functions in addition to convergent and divergent syntheses, click on chemistry and ligation innovations.
Read or Download Biomedical Applications of Peptide-, Glyco- and Glycopeptide Dendrimers, and Analogous Dendrimeric Structures PDF
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Extra info for Biomedical Applications of Peptide-, Glyco- and Glycopeptide Dendrimers, and Analogous Dendrimeric Structures
Another convincing example for a cluster effect in FimH binding was shown by employing mannosylated lysine-based MAGs . The relative inhibitory potencies of the di-, tetra-, octa-, and hexadecavalent mannosylated MAGs increased with growing generations from 455 over 2000 and 3571 to 11111, respectively . In spite of the fact that the avidity did not grow logarithmically, it rose to a much greater extent than it would by a linear increase with respect to the increasing valency. This increase of activity is called “cluster effect” or “multivalent effect” [10, 20, 34, 60, 63, 75, 87, 90, 91, 97, 116, 117, 126, 134].
Tetrahedron Lett. 50(42), 5816–5819 (2009) 65. : Preparation and multivalently enhanced guest-binding affinity of water-soluble cyclophane heptadecamers. J. Org. Chem. 73(8), 3205–3211 (2008) 66. : One-pot synthesis of multivalent arrays of mannose mono- and disaccharides. Tetrahedron 59(40), 7983–7996 (2003) 67. : High-affinity peptide-based collagen targeting using synthetic phage mimics: From phage display to dendrimer display. J. Am. Chem. Soc. 131(33), 11,683–11,685 (2009) 68.
Multivalent glycocluster design through directed evolution. Angew. Chem. Int. Ed. 50(47), 11238–11242 (2011) 62. : Effective encapsulation of a new cationic gadolinium chelate into apoferritin and its evaluation as an MRI contrast agent. Nanomedicine 7(5), 638–646 (2011) 63. : Analysis of GM3-Gg3 interaction using clustered gycoconjugate models constructed from glycolipid monolayers and artificial glycoconjugate polymers. Glycoconj. J. 21(3–4), 139–148 (2004) 64. : Mesomolecules from molecules to materials.