Advanced Inorganic Fluorides: Synthesis, Characterization by T. Nakajima, B. Žemva, A. Tressaud

By T. Nakajima, B. Žemva, A. Tressaud

This ebook summarizes fresh progresses in inorganic fluorine chemistry. Highlights contain new points of inorganic fluorine chemistry, reminiscent of new artificial tools, buildings of latest fluorides and oxide fluorides, their actual and chemical houses, fluoride catalysts, floor transformations of inorganic fabrics through fluorination method, new strength conversion fabrics and business purposes.

Fluorine has rather special houses (highest electronegativity; very small polarizability). actually, fluorine is so reactive that it varieties fluorides with all components other than with the lightest noble gases helium, neon and argon. initially, as a result of its excessive reactivity, fluoride chemistry confronted many technical problems and remained undeveloped for a few years. Now, despite the fact that, plenty of fluorine-containing fabrics are at the moment produced for sensible makes use of on an business scale and their functions are quickly extending to many fields.

Syntheses and constitution analyses of thermodynamically volatile high-oxidation-state fluorides have drastically contributed to inorganic chemistry during this decade. Fluoride catalysts and floor alterations utilizing fluorine are constructing a brand new box of fluorine chemistry and may permit new syntheses of varied compounds. The learn on inorganic fluorides is now contributing to many chemical power conversion procedures similar to lithium batteries. in addition, new theoretical techniques to making a choice on the digital buildings of fluorine compounds also are progressing. at the business entrance, using inorganic fluorine compounds is consistently expanding, for instance, in semi-conductor undefined.

"Advanced Inorganic Fluorides: Synthesis, Characterization and purposes" specializes in those new good points in inorganic fluorine chemistry and its business functions. The authors are notable specialists of their fields, and the contents of the publication may still turn out to be of helpful tips to all chemists, graduates, scholars and researchers within the box of fluorine chemistry.

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2Is+AsF6 - + AsF3 I42+(AsF6-)2 + AsF3 I42+(Sb3F14-)(SbF6-) SezI4(AsF6)2 ~ 8 0 2 -t" AsF3 Se612(AsF6)2 ~ 2SO2 + AsF3 Se214(SbzFI 1)2 S7X+MF6 - + AMF6 + 1/8S8 [218] [219] [2191 [220] [221] [220] [222] SO2,0~ SO2, -25-~'C 2CF3SBr2+SbF6 - + SbF3 2 [Ln(SO2)3](AsF6)3 q- 3AsF3 [223] [224] SO2/AsF3 [W(CO)4Te3][SbF6]2 + . . Sn(SbF6)2 ~ 2AsF3 2SeC13AsF6 + AsF3 S42+(Sb2FI 1-)2 + SbF3-SbF5 2S7Br+AsF6 - + AsF3 + 1/4S8 [225] [226] [227] [228] [229] .... T. T. T. T. T. T. T. T. 26 ion acceptor than BrF5 but shows remarkable ability to coordinate anions in quite surprising ways.

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